Trska, Petr published the artcileSubstituent effects on the carbon-13 NMR chemical shifts of aza- and triazaadamantanes, Application of 1,3,5-Triazaadamantan-7-amine, the publication is Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, H: Analyticka Chemie (1984), 29-40, database is CAplus.
13C NMR chem. shifts were studied for 13 N-substituted 1-aza- and 11 1,3,5-triazaadamantane derivatives The effects of substitution at the N for the former and at C-7 for the latter compounds were examined The ¦Á-C atoms in azaadamantanes were influenced in the same manner as the ¦Â-carbons in 1-substituted adamantanes. Similar results were obtained for 7-substituted triazaadamantanes. The substituent-chem.-shift (SCS) contributions for the 1-azaadamantane derivatives did not correlate simply with the electron densities obtained by the EHT method. Factor anal. was applied to 9 1-azaadamantanes, and the charges at the ¦Á, ¦Â and ¦Ã C atoms were established to be the decisive factors. Based on these data, the chem. shifts for a compound in this series were calculated with reasonable accuracy using the SCS matrix of the remaining 8 compounds
Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, H: Analyticka Chemie published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C5H11NO2S, Application of 1,3,5-Triazaadamantan-7-amine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia