Chan, Ka-Wang published the artcileDi- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands, COA of Formula: C15H24S, the publication is Journal of Organometallic Chemistry (2016), 151-157, database is CAplus.
Treatment of Ru(NO)Cl3 with NaSC6F4H (C6F4HSH = 2,3,5,6-tetrafluorothiophenol) afforded the hydroxo-bridged dimer Na(H2O)2[Ru(NO)(SC6HF4)2]2(¦Ì-SC6HF4)2(¦Ì-OH) (Na(H2O)21), in which the {Na(H2O)2}+ moiety binds to the diruthenium core via the ¦Ì-hydroxo ligand and three ortho F atoms of the thiolate ligands. Metathesis of Na(H2O)21 with Bu4NBr and Ph4PCl afforded Na-free (Bu4N)[1] and (Ph4P)[1], resp. Treatment of Ru(NO)Cl3 with NaSBut afforded the trinuclear oxo-sulfido cluster Na(H2O)2[Ru(NO)(SBut)(¦Ì-SBut)]3(¦Ì3-S)(¦Ì3-O) (Na(H2O)22) that contains a trinuclear {Ru3(SBut)3} core capped by a ¦Ì3-oxo and a ¦Ì3-sulfido ligand. The {Na(H2O)2}+ moiety binds to the triruthenium core via the ¦Ì3-oxo and two terminal thiolate ligands. Metathesis of Na(H2O)22 with Bu4NBr gave (Bu4N)[2]. Treatment of Ru(NO)Cl3 with NaStipp (tipp = 2,4,6-triisopropylphenyl) gave mononuclear Ru(NO)(Stipp)3(tippSH) (3). The crystal structures of Na(H2O)21, (Ph4P)[1], and Na(H2O)22 were determined
Journal of Organometallic Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, COA of Formula: C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia