Occhialini, Gino published the artcileCatalytic, contra-Thermodynamic Positional Alkene Isomerization, Product Details of C15H24S, the publication is Journal of the American Chemical Society (2022), 144(1), 145-152, database is CAplus and MEDLINE.
The discovery of a dual catalyst system that promotes contra-thermodn. positional alkene isomerization under photochem. irradiation, providing access to terminal alkene isomers, e.g., (2-methylallyl)benzene directly from conjugated, internal alkene, e.g., (2-methylpropenyl)benzene starting materials was reported. The utility of the method is demonstrated in the deconjugation of diverse electron-rich/electron-poor alkenes and through strategic application to natural product synthesis, e.g., (-)-nopinone. Mechanistic studies are consistent with a regiospecific bimol. homolytic substitution (SH2′) mechanism proceeding through an allyl-cobaloxime intermediate.
Journal of the American Chemical Society published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Product Details of C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia