Kim, Hyunwoo published the artcileA Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C-H Amination Using Azidoformates, Formula: C4H12ClNO, the publication is ACS Catalysis (2016), 6(9), 5922-5929, database is CAplus.
Described herein is the development of Ir(III)-catalyzed direct C-H amination using azidoformates as a readily deprotectable amino source. Substrates with unactivated Me C(sp3)-H and aromatic or olefinic C(sp2)-H bonds were smoothly reacted by the iridium-based catalyst system to provide the corresponding primary alkylamines and anilines upon the subsequent removal of N-protecting groups, such as Boc, Fmoc, Cbz, pNZ, or Troc. A brief mechanistic study and synthetic applications are also presented.
ACS Catalysis published new progress about 6084-58-8. 6084-58-8 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is O-Isobutylhydroxylamine hydrochloride, and the molecular formula is C4H12ClNO, Formula: C4H12ClNO.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia