Wang, Wei-Chi published the artcilePalladacycles bearing tridentate CNS-type benzamidinate ligands as catalysts for cross-coupling reactions, Name: 2-(Methylthio)ethanamine hydrochloride, the publication is Dalton Transactions (2012), 41(10), 3022-3029, database is CAplus and MEDLINE.
Three pendant benzamidines, [PhC(:NPh){NH(E)}] [E = (CH2)2SMe (1); (CH2)2StBu (2); o-C6H4SMe (3)], are described. Reactions of 1, 2 or 3 with one molar equiv Pd(OAc)2 in CH2Cl2 give the palladacyclic complexes [PhC{NH(¦Ç1-C6H4)}{:N(E)}]Pd(OAc) [E = (CH2)2SMe (4); (CH2)2StBu (5); o-C6H4SMe (6)], as mononuclear Pd complexes, resp. A minor product described as 5‘, {[PhC{NPh}{N(CH2)2StBu}]Pd(OAc)}2, was isolated as a benzamidinate-bridged dinuclear Pd complex upon recrystallizing from Et2O/hexane solution Treatment of 1, 2 or 3 with one molar equiv PdCl2 in the presence of NEt3 in CH2Cl2 gives the palladacyclic complexes [PhC{NH(¦Ç1-C6H4)}{:N(E)}]PdCl [E = (CH2)2SMe (7); (CH2)2StBu (8); o-C6H4SMe (9)], as mononuclear Pd complexes, resp. The crystal and mol. structures are reported for compounds 5, 5‘ and 6–8. The application of these palladacyclic complexes to the Suzuki and Heck coupling reactions was examined
Dalton Transactions published new progress about 6950-53-4. 6950-53-4 belongs to catalysis-chemistry, auxiliary class Salt,sulfides,Amine,Aliphatic hydrocarbon chain, name is 2-(Methylthio)ethanamine hydrochloride, and the molecular formula is C12H10FeO4, Name: 2-(Methylthio)ethanamine hydrochloride.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia