Kelly, Donovan P.’s team published research in Australian Journal of Chemistry in 22 | CAS: 1798-04-5

Australian Journal of Chemistry published new progress about 1798-04-5. 1798-04-5 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(4-(tert-Butyl)phenoxy)acetic acid, and the molecular formula is C12H16O3, COA of Formula: C12H16O3.

Kelly, Donovan P. published the artcilePhotochemical rearrangement of aromatic ethers, COA of Formula: C12H16O3, the publication is Australian Journal of Chemistry (1969), 22(5), 977-91, database is CAplus.

The irradiation of various types of aromatic ethers with uv light yields o- and p-substituted phenols, resulting from C-O bond fission followed by recombination of the 2 fragments. Also formed in these photolyses was the parent phenol, produced presumably by abstraction of H from the solvent by the aryloxy fragment. The ethers investigated were aryloxyacetic acids, allyl aryl ethers, benzyl phenyl ether, and diphenyl ether. Mixture experiments have shown that for both the aryloxyacetic acids and allyl aryl ethers the rearrangement is intramol. and most probably proceeds by formation of a radical-pair enclosed in a solvent cage.

Australian Journal of Chemistry published new progress about 1798-04-5. 1798-04-5 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(4-(tert-Butyl)phenoxy)acetic acid, and the molecular formula is C12H16O3, COA of Formula: C12H16O3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia