Bardin, V. V.’s team published research in Sibirskii Khimicheskii Zhurnal in | CAS: 1206-46-8

Sibirskii Khimicheskii Zhurnal published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.

Bardin, V. V. published the artcileInteraction of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino)phosphines. 3. Reactions of bromopentafluorobenzene with P(NEt2)3 and Me2SiXY, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Sibirskii Khimicheskii Zhurnal (1992), 52-5, database is CAplus.

The reactions of C6F5Br (I) with Me2SiXY (X = Cl, Br, I; Y = Me, Bu, Ph, C6F5) and P(NEt2)3 (II) gave C6F5SiMe2Y in 60-77% yield. Me2CHSiMe2Cl reacted with I and II to give the analogous product in only 23% yield. PhSiMe2F, PhSiMe2OEt, and C6F5SiMe2OEt were unreactive, and Me2SiClOEt was converted to C6F5SiMe2OEt and (C6F5)2SiMe2.

Sibirskii Khimicheskii Zhurnal published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia