Satge, Jacques published the artcileInsertion reaction of germanium fluoride (GeF2) into a variety of ¦Ò type bonds, Application In Synthesis of 312-40-3, the publication is Comptes Rendus des Seances de l’Academie des Sciences, Serie C: Sciences Chimiques (1974), 278(21), 1309-12, database is CAplus.
The in-sertion of F2Ge into RX gave RGeXF2 (R = Et, MeOCH2; X = Cl, Br, iodo). Phenylchlorosilanes, Ph3SiCl, Ph2SiCl2, and Ph-SiCl3 inserted F2Ge to give Ph3SiGeF2Cl, Ph2Si(GeF2Cl)2, andPhSi(GeF2Cl)3, resp. A 95:5% mixture of the diastereomers of 2-chloro-5-methyl-2-phenyl-l-oxa-2-germacyclopentane inserted di-fluorogermylene stereospecifically to give a 95:5% mixture of the diastereomers of oxadigermacyclohexane I. Butadiene added methoxyfluorogermylene to give 1-fluoro-1-methoxy-2,3-di-methylgermacyclopent-3-ene (II).
Comptes Rendus des Seances de l’Academie des Sciences, Serie C: Sciences Chimiques published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C12H10F2Si, Application In Synthesis of 312-40-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia