Cabrero-Antonino, Jose R. published the artcileA general protocol for the reductive N-methylation of amines using dimethyl carbonate and molecular hydrogen: mechanistic insights and kinetic studies, Category: catalysis-chemistry, the publication is Catalysis Science & Technology (2016), 6(22), 7956-7966, database is CAplus.
Herein, a general and selective ruthenium-catalyzed reductive methylation of amines using di-Me carbonate as a C1 source and mol. hydrogen as a reducing agent has been reported. Notably, this methodol. allows N-methylated tertiary aromatic and aliphatic amines to be obtained with good to excellent yields using a green, non-toxic and biodegradable carbon source in the presence of an in situ formed Ru/Triphos complex. The catalytic protocol presented here opens the possibility of developing new sustainable processes for the selective synthesis of N-Me substituted amines using mol. hydrogen. Mechanistic and kinetic studies have been carried out in order to understand the pathways involved in the general reaction mechanism for the N-methylation of aniline.
Catalysis Science & Technology published new progress about 2909-77-5. 2909-77-5 belongs to catalysis-chemistry, auxiliary class Amine,Benzene, name is 2,6-Diisopropyl-N,N-dimethylaniline, and the molecular formula is C14H23N, Category: catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia