Kafka, Z. published the artcileNitrogen compounds of adamantane. IV. Paper chromatography of azaadamantane derivatives, Computed Properties of 14707-75-6, the publication is Collection of Czechoslovak Chemical Communications (1974), 39(11), 3268-71, database is CAplus.
The separation of 1-azaadamantane (I) and its quaternary salts, 1,3-diazaadamantane (II) and its tetrasubstituted derivatives, and 1,3,5-triazaadamantane (III) and its derivatives was studied by descending chromatog. on Whatman number 1 paper at 20¡ã. The Rf values in various solvents are tabulated. Good separation of I and its quaternary salts was achieved by using a solvent system containing HCl and an alc. with a branched chain, e.g. iso-PrOH or 2-methyl-1-propanol. For the separation of II and its derivatives, HCl was replaced by HOAc; but the best results were obtained by using 20:1:4 EtOH-NH4OH(25%)-H2O. For the separation of III and its derivatives a neutral solvent system, i.e. alcs.-H2O was used. For the detection of I and II and their derivatives, Dragendorff’s reagent was used. To detect III and its derivatives, which do not contain either a primary or a secondary amino group, a solution of 4-dimethylaminobenzaldehyde in EtOH and HCl was used. The quaternary salts of I and derivatives of III were applied as aqueous solutions; derivatives of II were dissolved in HOAc or in EtOH-HCl.
Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Computed Properties of 14707-75-6.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia