Wuensch, Christiane published the artcilePushing the equilibrium of regio-complementary carboxylation of phenols and hydroxystyrene derivatives, HPLC of Formula: 17351-61-0, the publication is Journal of Biotechnology (2013), 168(3), 264-270, database is CAplus and MEDLINE.
The enzymic carboxylation of electron-rich aromatics, which represents a promising ‘green’ equivalent to the chem. Kolbe-Schmitt reaction, is thermodynamically disfavored and is therefore impeded by incomplete conversions. Optimization of the reaction conditions, such as pH, temperature, substrate concentration and the use of organic co-solvents and/or ionic liquids allowed to push the conversion in favor of carboxylation by a factor of up to 50%. Careful selection of the type of bicarbonate salt used as CO2 source was crucial to ensure optimal activities. Among two types of carboxylases tested with their natural substrates, benzoic acid decarboxylase from Rhizobium sp. proved to be significantly more stable than phenolic acid decarboxylase from Mycobacterium colombiense; it tolerated reaction temperatures of up to 50 ¡ãC and substrate concentrations of up to 100 mM and allowed efficient biocatalyst recycling.
Journal of Biotechnology published new progress about 17351-61-0. 17351-61-0 belongs to catalysis-chemistry, auxiliary class Phase Transfer Catalyst, name is Tetraethylammonium hydrogencarbonate, and the molecular formula is C7H10O4, HPLC of Formula: 17351-61-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia