Chen, Wen-Ching published the artcileExpanding the ligand framework diversity of carbodicarbenes and direct detection of boron activation in the methylation of amines with CO2, HPLC of Formula: 2909-77-5, the publication is Angewandte Chemie, International Edition (2015), 54(50), 15207-15212, database is CAplus and MEDLINE.
A simple and convergent synthetic strategy used to increase the diversity of the carbodicarbenes I (7a–f, R1 = 2-pyridyl, iPr, 2,6-iPr2C6H3; R2 = Me, iPr, 2,6-iPr2C6H3; R3 = Me, iPr) ligand framework through incorporation of unsym. pendant groups is reported. The carbenes 7a–f catalyze 9-BBN-promoted reductive methylation of primary and secondary amines with carbon dioxide. Structural anal. and spectroscopic studies of ligands and their Rh complexes are reported. Reactivity studies reveal carbodicarbenes as competent organocatalysts for amine methylation using CO2 as a synthon. A unique B-H-activated boron-carbodicarbene complex was isolated as a reaction intermediate, providing mechanistic insight into the CO2 functionalization process.
Angewandte Chemie, International Edition published new progress about 2909-77-5. 2909-77-5 belongs to catalysis-chemistry, auxiliary class Amine,Benzene, name is 2,6-Diisopropyl-N,N-dimethylaniline, and the molecular formula is C14H23N, HPLC of Formula: 2909-77-5.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia