Kimberley, Louis published the artcileThe Origin of Catalytic Benzylic C-H Oxidation over a Redox-Active Metal-Organic Framework, SDS of cas: 457-68-1, the publication is Angewandte Chemie, International Edition (2021), 60(28), 15243-15247, database is CAplus and MEDLINE.
Selective oxidation of benzylic C-H compounds to ketones is important for the production of a wide range of fine chems., and is often achieved using toxic or precious metal catalysts. Herein, we report the efficient oxidation of benzylic C-H groups in a broad range of substrates under mild conditions over a robust metal-organic framework material, MFM-170, incorporating redox-active [Cu2II(O2CR)4] paddlewheel nodes. A comprehensive investigation employing ESR (EPR) spectroscopy and synchrotron X-ray diffraction has identified the critical role of the paddlewheel moiety in activating the oxidant tBuOOH (tert-Bu hydroperoxide) via partial reduction to [CuIICuI(O2CR)4] species.
Angewandte Chemie, International Edition published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C13H10F2, SDS of cas: 457-68-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia