Kuzhalmozhi Madarasi, Packirisamy published the artcileGrignard reagent dictated copper(I) phosphines catalyzed reductive coupling of diazo compounds: The chemistry beyond carbene generation, Category: catalysis-chemistry, the publication is Applied Organometallic Chemistry (2022), 36(2), e6522, database is CAplus.
Copper-dppf catalyzed reductive coupling of diazo compounds through a terminal nitrogen is reported. However, copper catalysts are known to produce carbene from diazo compounds Reaction conditions play an important role in formation of diazine over carbene generation. Several control experiments were conducted to understand the reaction mechanism and the authors found that formation of a copper-Mg heterobimetallic complex is responsible for the observed reactivity pattern. The reaction produced diazine as a reductive coupling product along with biphenyl as a byproduct. All synthesized diazines were characterized fully by using anal. and spectroscopic techniques.
Applied Organometallic Chemistry published new progress about 613-33-2. 613-33-2 belongs to catalysis-chemistry, auxiliary class Benzene, name is 4,4′-Dimethyldiphenyl, and the molecular formula is C14H14, Category: catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia