Palaniappan, An. published the artcileKinetics and mechanism of oxidation of some meta- and para- substituted phenoxyacetic acids by N-chloropiperazine-2,5-dione in non-aqueous medium, SDS of cas: 1798-04-5, the publication is Asian Journal of Chemistry (2002), 14(2), 607-613, database is CAplus.
The kinetics of oxidation of a number of meta- and para- substituted phenoxyacetic acids by N-chloropiperazine-2,5-dione (NCPD) were studied in methanol medium. The reaction shows unit order dependence with respect to oxidant and the order with respect to substrate varies depending on the nature of the substituent present in the ring. The rate is showing an inverse order of dependence with respect to [TsOH]. The rate increases with decrease in the percentage of methanol. Increase in ionic strength has no effect on the reaction rate. From the kinetic data obtained the activation parameters were computed and a suitable mechanism was proposed in accordance with multiparameter correlation anal.
Asian Journal of Chemistry published new progress about 1798-04-5. 1798-04-5 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(4-(tert-Butyl)phenoxy)acetic acid, and the molecular formula is C12H16O3, SDS of cas: 1798-04-5.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia