Tardiff, Bennett J. published the artcileBuchwald-Hartwig amination of (hetero)aryl chlorides by employing Mor-DalPhos under aqueous and solvent-free conditions, Recommanded Product: 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, the publication is European Journal of Organic Chemistry (2012), 2012(21), 3972-3977, S3972/1-S3972/127, database is CAplus.
Aryl amines e. g., I are prepared via Buchwald-Hartwig amination of (hetero)aryl chlorides with primary or secondary amines conducted either under aqueous conditions without the use of co-solvents and/or surfactants or under solvent-free conditions using [Pd(cinnamyl)Cl]2/Mor-DalPhos catalyst system. We have established that reactions of this type can be conducted without the rigorous exclusion of air, and in the case of the solvent-free reactions, we have demonstrated that appropriately selected liquid and solid reagents can be employed successfully.
European Journal of Organic Chemistry published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C13H13N5O, Recommanded Product: 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia