Saidalimu, Ibrayim published the artcileSuccessive C-C bond cleavage, fluorination, trifluoromethylthio- and pentafluorophenylthiolation under metal-free conditions to provide compounds with dual fluoro-functionalization, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Chemical Science (2016), 7(3), 2106-2110, database is CAplus and MEDLINE.
The selective C-C bond cleavage and simultaneous formation of two C-F bonds and one C-S bond in ¦Â-keto esters with nucleophilic fluorination reagents such as DAST under metal-free/catalyst-free conditions was disclosed. Double fluorination at two remote carbons with addnl. dialkylamino-sulfenylation provided unique fluorinated compounds in good to high yields. This method was applied for the successive C-C bond cleavage/fluorination/trifluoromethylthiolation of ¦Â-keto esters using trifluoromethyl-DAST (CF3-DAST) providing different type of fluorinated and trifluoromethylthiolated compounds via a shunt pathway. Doubly fluoro-functionalized compounds obtained in these reactions were unique and difficult to synthesize by other methods.
Chemical Science published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia