Leibler, Isabelle Nathalie-Marie published the artcileA general strategy for C(sp3)-H functionalization with nucleophiles using methyl radical as a hydrogen atom abstractor, HPLC of Formula: 457-68-1, the publication is Nature Communications (2021), 12(1), 6950, database is CAplus and MEDLINE.
A strategy that transforms C(sp3)-H bonds into carbocations via sequential hydrogen atom transfer (HAT) and oxidative radical-polar crossover were discussed. The resulting carbocation was functionalized by a variety of nucleophiles-including halides, water, alcs., thiols, an electron-rich arene and an azide-to effect diverse bond formations. Mechanistic studies indicated that HAT was mediated by Me radical-a previously unexplored HAT agent with differing polarity to many of those used in photoredox catalysis-enabling new site-selectivity for late-stage C(sp3)-H functionalization.
Nature Communications published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C13H10F2, HPLC of Formula: 457-68-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia