Xiong, Zhichao published the artcileEnantioselective synthesis of chiral multicyclic ¦Ã-lactones via dynamic kinetic resolution of racemic ¦Ã-keto carboxylic acids, Computed Properties of 2051-95-8, the publication is Organic Chemistry Frontiers (2020), 7(1), 104-108, database is CAplus.
Ru-Catalyzed asym. transfer hydrogenation of ¦Ã-keto carboxylic acids was achieved by using the formic acid-triethylamine azeotrope as the hydrogen source, affording chiral multicyclic ¦Ã-lactones in high yields with excellent diastereo- and enantioselectivities (up to 92% yield, >20 : 1 dr and 99% ee). This method provided a highly efficient approach to obtain valuable multicyclic ¦Ã-lactones through a reduction/lactonization sequence. Moreover, a concise synthetic route to obtain bioactive mols. (+)-GR24 and (+)-epi-GR24 had also been developed by using this methodol. as a key step.
Organic Chemistry Frontiers published new progress about 2051-95-8. 2051-95-8 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ketone, name is 3-Benzoylpropionicacid, and the molecular formula is C9H17NO, Computed Properties of 2051-95-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia