Liu, Xiao-Jun published the artcileThe influence of NHCs on C-Si and C-C reductive elimination: a computational study of the selectivity of Ni-catalyzed C-H activation of arenes with vinylsilanes, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Chemical Communications (Cambridge, United Kingdom) (2018), 54(57), 7912-7915, database is CAplus and MEDLINE.
D. functional theory calculations were performed to investigate the mechanism and origins of the NHC-controlled selectivity of Ni-catalyzed C-H activation of arenes with vinylsilanes. The key to the selectivity is the different impacts of NHCs on the C-Si/C-C reductive elimination of the square-planar/T-shaped intermediate.
Chemical Communications (Cambridge, United Kingdom) published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Recommanded Product: Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia