Choi, Zel-Ho’s team published research in Zeitschrift fuer Anorganische und Allgemeine Chemie in 625 | CAS: 1206-46-8

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, COA of Formula: C9H9F5Si.

Choi, Zel-Ho published the artcileOn the chemistry of fluoroorgano derivatives of Group 13 elements. Part 2. Synthesis and characterization of the 1:1-adducts of In(C6F5)3 with acetonitrile, glyme, and DMAP [DMAP = 4-(N,N-dimethylamino)pyridine], and [PNP][In(C6F5)4] [PNP = bis(triphenylphosphine)immonium]. The crystal structure of [PNP][In(C6F5)4], COA of Formula: C9H9F5Si, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (1999), 625(8), 1287-1292, database is CAplus.

In(C6F5)3.MeCN and In(C6F5)3.glyme were synthesized from InCl3 and Cd(C6F5)2 in MeCN or glyme in 43% and 35% yield, resp. Replacement of MeCN or Et2O by DMAP yielded the corresponding 1:1-adduct. [PNP][In(C6F5)4] was best prepared from the corresponding Cs salt which was best synthesized from the reaction of stoichiometric amounts of In(C6F5)3.MeCN, Me3SiC6F5, and CsF in good yield. [PNP][In(C6F5)4] crystallizes in the triclinic space group P1? [a 1104.9(4), b 1442.4(6), c 1833.8(8) pm, ¦Á 110.87(2), ¦Â 92.04(3), ¦Ã 96.55(3)¡ã, Z = 2].

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, COA of Formula: C9H9F5Si.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia