Hegemann, Corinna published the artcileSynthetic and Structural Investigations on the Reactivity of the Cd-I Bond in [ICd{Zr2(OPri)9}] to Construct New Mixed-Metal Alkoxides, COA of Formula: C9H9F5Si, the publication is Organometallics (2013), 32(6), 1654-1664, database is CAplus.
New mixed-metal alkoxides [XCd{Zr2(OPri)9}]n (X = -C2F5, -C6F5, -C6F4-4-H, -NO3, -NCO, -SO3CF3, -O2CCF3, -O2CC2F5, -O2CCH3, -ClO4, -CN, -SO4; n = 1, 2) were obtained by the scission of the Cd-I bond in the iodo heterobimetallic isopropoxide [ICd{Zr2(OPri)9}] (1), whereby the underlying synthetic strategies involve metathesis reactions with Ag salts or Lewis acid-base interactions between the Bronsted acid [Zr(OPri)4(HOPri)]2 and bis(fluoroorgano)cadmium (Cd(Rf)2) compounds The new compounds were characterized by multinuclear NMR spectroscopy, elemental anal., and mass spectrometry. The results of x-ray diffraction anal. of [(F5C6)Cd{Zr2(OPri)9}] (2), [(4-H-F4C6)Cd{Zr2(OPri)9}] (3), [(F5C2)Cd{Zr2(OPri)9}]2 (4), [(ONO2)Cd{Zr2(OPri)9}]2 (5), [(CH3CO2)Cd{Zr2(OPri)9}] (6), [(O2ClO2)(H5C3N)Cd{Zr2(OPri)9}] (7), [(¦Ì-O2ClO2)Cd{Zr2(OPri)9}]2 (8), [(¦Ì-O2CCF3)Cd{Zr2(OPri)8(O2CCF3)}]2 (9), [(¦Ì-O2CC2F5)Cd{Zr2(OPri)8(O2CC2F5)}]2 (10), [(¦Ì(O,N)-OCN)Cd{Zr2(OPri)9}]2 (11), and [(¦Ì-O2SOCF3)Cd{Zr2(OPri)9}]2 (12) revealed the mol. framework to be formally constituted by tetradentate coordination of a nonaisopropoxo dizirconate unit, {Zr2(OPri)9}–, to a CdX+ unit. In solution and in the solid state, 1–7 exist as monomers, whereas compounds 8–12 form dimers.
Organometallics published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, COA of Formula: C9H9F5Si.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia