Thirupugalmani, K. published the artcileInfluence of polar solvents on growth of potentially NLO active organic single crystals of N-benzyl-2-methyl-4-nitroaniline and their efficiency in terahertz generation, Recommanded Product: N-Benzyl-2-methyl-4-nitroaniline, the publication is CrystEngComm (2017), 19(19), 2623-2631, database is CAplus.
We report on the growth of N-benzyl-2-methyl-4-nitroaniline (BNA) crystals by a solution growth method using certain polar protic and aprotic solvents (single or mixed). It was observed that the morphol. of the BNA crystals could be influenced by the solvents used and that the growth was, with certain exceptions, predominant along the crystallog. b axis. Attempts to grow large BNA crystals from these solvents showed that the majority of these polar solvent mols. tended to get adsorbed preferentially along the polar +c and/or -c axes/axis. The bulk and surface qualities of the grown crystals were observed to be influenced by the solvents employed to grow the BNA crystals and the results of THz measurements obtained for the crystals grown from selected solvents were also found to corroborate these observations. A systematic approach has shown that the BNA crystals grown from one of the polar aprotic solvents, which is presumably reported for the first time for this crystal, exhibited a relatively higher THz efficiency. It is further understood that this particular solvent created a favorable solute-solvent environment at the progressing crystal-solution interface which improved the overall quality of the BNA single crystals and resulted in the significant enhancement in the THz efficiencies.
CrystEngComm published new progress about 201157-13-3. 201157-13-3 belongs to catalysis-chemistry, auxiliary class Nitro Compound,Amine,Benzene, name is N-Benzyl-2-methyl-4-nitroaniline, and the molecular formula is C12H10F2Si, Recommanded Product: N-Benzyl-2-methyl-4-nitroaniline.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia