Sekar, K. G.’s team published research in Oxidation Communications in 34 | CAS: 1798-04-5

Oxidation Communications published new progress about 1798-04-5. 1798-04-5 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(4-(tert-Butyl)phenoxy)acetic acid, and the molecular formula is C15H21BO2, Synthetic Route of 1798-04-5.

Sekar, K. G. published the artcileKinetics of oxidation of phenoxyacetic acids by nicotinium dichromate, Synthetic Route of 1798-04-5, the publication is Oxidation Communications (2011), 34(2), 314-319, database is CAplus.

The kinetics of oxidation of phenoxyacetic acid and several para- and meta-substituted phenoxyacetic acids by nicotinium dichromate (NDC) in the presence of perchloric acid was studied in 60% (volume/volume) aqueous acetic acid. The reaction shows unit order dependence each with respect to oxidant and substrate. The order with respect to hydrogen ion concentration is two. The rate of oxidation increases with increase in the percentage of acetic acid and increase in ionic strength has negligible effect on the rate. The reaction does not induce the polymerization of acrylonitrile. The addition of Mn2+ ion had a noticeable catalytic effect on the reaction rate. In general, electron-releasing substituents accelerate the rate while electron attracting substituents retard the rate and the rate data obey the Hammett relation.

Oxidation Communications published new progress about 1798-04-5. 1798-04-5 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(4-(tert-Butyl)phenoxy)acetic acid, and the molecular formula is C15H21BO2, Synthetic Route of 1798-04-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia