Wu, Gongde published the artcileHighly efficient one-pot synthesis of 2,4-disubstituted thiazoles using Au(I) catalyzed oxidation system at room temperature, Formula: C30H42NOP, the publication is Catalysts (2016), 6(8), 126/1-126/9, database is CAplus.
A gold complex catalysts with Mor-DalPhos ligands were successfully prepared using mesylates as counter ions. Seven ammonium sulfonates were synthesized to promote the production of intermediate sulfonyloxymethyl ketone. It was found that low-acidity N,N-dimethylbenzenaminium methanesulfonate showed excellent activity in the reaction. Furthermore, the catalysts effectively avoided the loss of activity due to the low acidity. Various thioamides were directly added to the resulting reaction mixture without the separation of intermediate product. Then, twenty kinds of 2,4-disubstituted thiazoles were efficiently synthesized at room temperature with the highest yield of 91%. An efficiency and mild gold-catalyzed oxidation system for the one-pot synthesis of thiazole and its derivatives was provided.
Catalysts published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C10H18O, Formula: C30H42NOP.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia