Armstrong, Susan K.’s team published research in Tetrahedron Letters in 32 | CAS: 4141-48-4

Tetrahedron Letters published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Category: catalysis-chemistry.

Armstrong, Susan K. published the artcileStereocontrolled synthesis of homoallylic amines using phosphine oxides and isoxazolines, Category: catalysis-chemistry, the publication is Tetrahedron Letters (1991), 32(33), 4171-4, database is CAplus.

Allylic diphenylphosphine oxides, e.g., Ph2P(O)CHMeCH:CH2, undergo stereoselective 1,3-dipolar cycloadditions with nitrile oxides, e.g., PhCNO to give ¦¤2-isoxazolines, e.g., I. These may be reduced, also stereoselectively, to ¦Ä-amino-¦Â-hydroxyalkyldiphenylphosphine oxides, e.g., II. Stereospecific Wittig-Horner type elimination of Ph2PO2– from the amino alcs., e.g., II, gives homoallylic amines, e.g., III, with controlled double bond geometry.

Tetrahedron Letters published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia