Edwards, Afarin’s team published research in Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) in | CAS: 14707-75-6

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Application of 1,3,5-Triazaadamantan-7-amine.

Edwards, Afarin published the artcileNitration of 7-substituted 1,3,5-triaza-adamantanes, Application of 1,3,5-Triazaadamantan-7-amine, the publication is Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) (1977), 1989-92, database is CAplus.

Nitrations of the triazaadamantanes I (R = NO2, NH2, Br, NHAc, N:CHC6H4OMe-4) with various nitrating mixtures are described. E.g., reaction of I (R = NO2) with HNO3-NH4NO3 (NAN) gave the diazacyclohexane derivative II (R = NO2, R1 = CH2N+H3NO3) whereas treatment with HNO3-H2SO4 (NS) gave the bicyclic product III. Similar treatment of I (R = NH2, Br) with NAN or NS, I (R = NHAc) with NAN, and I (R = N:CHC6H4OMe-4) with fuming HNO3 gave II [R = NHNO2, Br, R1 = CH2N+H3NO3; RR1 = CH2N(NO)2CH2NAc, CH2N(NO2)CH2NH, resp.]. The mechanism which is postulated for the nitration reactions is similar to that suggested by W. (1976) for the nitration of hexamine with HNO3.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Application of 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia