Gee, J. C. published the artcileKinetics of hydrogen peroxide oxidation of alkyl dimethyl amines, Application In Synthesis of 28056-87-3, the publication is Journal of the American Oil Chemists’ Society (1997), 74(1), 65-67, database is CAplus.
We measured the absolute rate constants for the hydrogen peroxide oxidation of two different octyl di-Me amines in isopropanol/water mixtures at 23¡ã. The amines were 1-octyl di-Me amine (1) and 2-ethylhexyl di-Me amine (2); their structures were analogous to those most often encountered in com. alkyl di-Me amine oxide production The observed first-order rate constants for the disappearance of amine across a range of H2O2 concentrations (0.5-8 M) indicated that the overall rate was first-order in amine and 3/2-order in H2O2. Calculations showed k1 = 0.16 M-1h-1, k2 = 0.046 M-1h-1, and k1/k2 = 3.5. The rates appeared to decrease with increasing steric hindrance around the nitrogen atom. We also investigated the effect of water on the reaction rates. When [H2O] < ?4.5 M in isopropanol, the rates increased with increasing [H2O]; for [H2O] > ?4.5 M, the rates were insensitive to [H2O].
Journal of the American Oil Chemists’ Society published new progress about 28056-87-3. 28056-87-3 belongs to catalysis-chemistry, auxiliary class Amine,Aliphatic hydrocarbon chain, name is 2-Ethyl-N,N-dimethylhexan-1-amine, and the molecular formula is C10H23N, Application In Synthesis of 28056-87-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia