Koch, Alexander’s team published research in Organometallics in 36 | CAS: 1206-46-8

Organometallics published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, SDS of cas: 1206-46-8.

Koch, Alexander published the artcileHydrocarbon-soluble bis(trimethylsilylmethyl)calcium and calcium-iodine exchange reactions at sp2-hybridized carbon atoms, SDS of cas: 1206-46-8, the publication is Organometallics (2017), 36(20), 3981-3986, database is CAplus.

Hydrocarbon-soluble and highly reactive [(L)xCa(CH2SiMe3)2] (2a, L = tetrahydropyran, x = 4; 2b,L = tmeda, x = 2) are synthesized by the metathesis reaction of Me3SiCH2CaI (1-I) with KCH2SiMe3. The stability of 2a in tetrahydropyran solution at 0¡ã is sufficiently high for subsequent chem. transformations. The reaction of ICH2SiMe3 with calcium in di-Et ether yields unique iodide-bridged cage compound [Ca3(¦Ì3-I)(¦Ì-I)3(¦Ì3-OEt)(CH2SiMe3)(OEt2)5] (3). We demonstrate that alkylcalcium complexes are valuable reagents for calcium-iodine exchange reactions at Csp2-I functionalities.

Organometallics published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, SDS of cas: 1206-46-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia