Li, Wen-Duo published the artcileBoryl Radical Activation of Benzylic C-OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis, Product Details of C14H14, the publication is Journal of the American Chemical Society (2022), 144(19), 8551-8559, database is CAplus and MEDLINE.
A new strategy for the direct cleavage of the C(sp3)-OH bond was developed via activation of free alcs. with neutral di-Ph boryl radical generated from sodium tetraphenylborate under mild visible light photoredox conditions. This strategy was verified by cross-electrophile coupling of free alcs. and carbon dioxide for the synthesis of carboxylic acids. Direct transformation of a range of primary, secondary, and tertiary benzyl alcs. to acids was achieved. Control experiments and computational studies indicate that activation of alcs. with neutral boryl radical undergoes homolysis of the C(sp3)-OH bond, generating alkyl radicals. After reducing the alkyl radical into carbon anion under photoredox conditions, the following carboxylation with CO2 affords the coupling product.
Journal of the American Chemical Society published new progress about 613-33-2. 613-33-2 belongs to catalysis-chemistry, auxiliary class Benzene, name is 4,4′-Dimethyldiphenyl, and the molecular formula is C14H14, Product Details of C14H14.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia