Tang, Kaluo published the artcileReactions of mononuclear copper complexes formed by insertion of CS2 into Cu-S bonds with various solvents. III. Formation and crystal structure of [CuI(PPh3)(Py)]2 and [CH2(C5H5N)2]2[Cu2I6], Synthetic Route of 22693-41-0, the publication is Beijing Daxue Xuebao, Ziran Kexueban (1995), 31(6), 695-702, database is CAplus.
Mononuclear Cu complexes with structures of (Ph3P)2Cu(S2CSR), formed by insertion of CS2 into Cu-S bonds, can react with a various solvents undergoing some nucleophilic reactions. [CuI(PPh3)(Py)]2 (I) and [CH2(C5H5N)2]2[Cu2I6] (II) were obtained from the reaction of starting material (R = But, C6H2Pr3i-2,4,6) with CH2I2-acetone mixed-solvent in the presence of pyridine and then self-assembly in the same solution Crystal data for I: space group C2/c,a = 26.112(6), b 14.499(3), c 11.357(2) ?, ¦Â 95.12(2)¡ã, Dc = 1.650 g/cm¡Þ3, Z = 4, R = 0.0334 fro 2182 independent reflections. Crystal data for II: space group P21/n, a 11.389(4), b 11.698(5), c 13.227(7) ?, ¦Â 114.99(4)¡ã, Dc = 2.563 g/cm3, Z = 0.0627 for 1891 independent reflection.
Beijing Daxue Xuebao, Ziran Kexueban published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C5H6BNO2, Synthetic Route of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia