Cai, Mingzhong’s team published research in Synthetic Communications in 52 | CAS: 118-90-1

Synthetic Communications published new progress about 118-90-1. 118-90-1 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Natural product, name is 2-Methylbenzoic acid, and the molecular formula is C8H8O2, Application of 2-Methylbenzoic acid.

Cai, Mingzhong published the artcileRecyclable palladium-catalyzed Suzuki coupling of aromatic triazine esters: A practical one-pot synthesis of aryl ketones from aromatic acids, Application of 2-Methylbenzoic acid, the publication is Synthetic Communications (2022), 52(7), 1079-1090, database is CAplus.

An efficient heterogeneous palladium-catalyzed Suzuki coupling of aromatic triazine esters I (Ar = 4-methylphenyl, naphthalen-1-yl, thiophen-2-yl, etc.) with arylboronic acids Ar1B(OH)2 (Ar1 = Ph, 3,5-dichlorophenyl, furan-2-yl, etc.) has been developed. The reaction proceeds smoothly in toluene at 110¡ãC using 2 mol% of MCM-41-bound bidentate phosphine palladium complex [MCM-41-2P-Pd(OAc)2] as catalyst and provides a novel and practical method for the synthesis of aryl ketones ArC(O)Ar1 starting from readily available aromatic acids ArCOOH in a one-pot procedure with moderate to excellent yields. The MCM-41-2P-Pd(OAc)2 catalyst can be reused at least seven times without any apparent decrease in its catalytic activity.

Synthetic Communications published new progress about 118-90-1. 118-90-1 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Natural product, name is 2-Methylbenzoic acid, and the molecular formula is C8H8O2, Application of 2-Methylbenzoic acid.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia