Shi, Jiang-Ling published the artcileFe-Promoted Chlorobenzylation of Terminal Alkynes through Benzylic C(sp3)-H Bond Functionalization, SDS of cas: 457-68-1, the publication is Organic Letters (2016), 18(6), 1238-1241, database is CAplus and MEDLINE.
A chlorobenzylation of terminal alkynes through Fe(II)-promoted benzylic C(sp3)-H bond functionalization in the presence of NCS as a chloride source was developed. Compared with previous methods to prepare polysubstituted alkenyl halides, the present procedure provides an efficient alternative with high atom and step economy under mild conditions. The transformation was established to proceed through a single-electron transfer (SET) process with benzyl cations as key intermediates.
Organic Letters published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C15H10O2, SDS of cas: 457-68-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia