Wang, Sheng published the artcileI2-Mediated oxidative bicyclization of 4-pentenamines to prolinol carbamates with CO2 incorporating oxyamination of the C=C bond, Application of 2,2-Diallylpent-4-en-1-amine, the publication is Green Chemistry (2017), 19(19), 4515-4519, database is CAplus.
A metal-free oxyamination reaction of alkenes with ambient CO2 has been reported. In the presence of I2 and DBU, CO2 is applied in situ as a protecting group to regulate the nucleophilicity of the amino group and facilitate the bicyclization of 4-pentenamines, e.g., 2,2-diphenylhex-5-en-1-amine with high chemoselectivity. Moreover, this reaction provided a feasible approach to prepare prolinol carbamates, e.g., 6,6-diphenyltetrahydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one with good tolerance of functional groups and high efficiency under mild conditions.
Green Chemistry published new progress about 928836-00-4. 928836-00-4 belongs to catalysis-chemistry, auxiliary class Alkenyl,Amine,Aliphatic hydrocarbon chain, name is 2,2-Diallylpent-4-en-1-amine, and the molecular formula is C9H9ClN2, Application of 2,2-Diallylpent-4-en-1-amine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia