Wu, Gongde published the artcileOne-step synthesis of methanesulfonyloxymethyl ketones via gold-catalyzed oxidation of terminal alkynes: A combination of ligand and counter anion enables high efficiency and a one-pot synthesis of 2,4-disubstituted thiazoles, Related Products of catalysis-chemistry, the publication is Advanced Synthesis & Catalysis (2014), 356(6), 1229-1234, database is CAplus.
The Au(I) complex of (2-morpholinophenyl)diadamantanylphosphine (Mor-DalPhos) as P,N-bidentate ligand and mesylate as counter ion catalyzed efficient oxidative transformations of various terminal alkynes into synthetically versatile [(methanesulfonyl)oxy]methyl ketones. The mild reaction conditions and high efficiency permit the one-pot synthesis of a range of valuable 2,4-disubstituted thiazoles by subjecting the resulting reaction mixture to a further condensation with thioamides under mild conditions.
Advanced Synthesis & Catalysis published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C8H10O2, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia