Citron, Joel D.’s team published research in Journal of Organic Chemistry in 36 | CAS: 312-40-3

Journal of Organic Chemistry published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C12H10F2Si, SDS of cas: 312-40-3.

Citron, Joel D. published the artcileReductions with organosilicon hydrides. III. Reduction of acyl fluorides to esters, SDS of cas: 312-40-3, the publication is Journal of Organic Chemistry (1971), 36(17), 2547-8, database is CAplus.

Aliphatic RCOF are heated with Et3SiH or (PhCH2)3SiH to give RCO2CH2R. Pentanoyl fluoride (I) is treated with Et3SiH and R1CHO is added to give Me(CH2)3CO2CH2R1 (R1 = alkyl, Ph); PhCN does not affect the reaction of I with Et3SiH and pentyl pentanoate is formed. Terephthaloyl fluoride reacts with Et3SiH to give polymer. Esters are not obtained when Ph2SiH2 is used.

Journal of Organic Chemistry published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C12H10F2Si, SDS of cas: 312-40-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia