Grudzinski, S.’s team published research in Lodz Towarz. Nauk., Wydzial III, Acta Chim. in 10 | CAS: 10517-44-9

Lodz Towarz. Nauk., Wydzial III, Acta Chim. published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Product Details of C3H12Cl2N2.

Grudzinski, S. published the artcileCyanomethyl esters. V. Reaction of cyanomethyl esters of carboxylic acids with cyanoethylhydrazine, Product Details of C3H12Cl2N2, the publication is Lodz Towarz. Nauk., Wydzial III, Acta Chim. (1965), 85-93, database is CAplus.

cf. CA 65, 681f. The appropriate cyanomethyl ester RCO2CH2CN{Alt}{179}(I) treated with H2-NNH(CH2)2CN (II) furnished the following RCONHNH-(CH2)2CN (R, % yield) and m.p. (b.p.) given: Me (III), 73, (b1.5 162-6¡ã); Et (IV), 73, (b1.5 158-62¡ã); 4-O2NC6H4, 55.5, 164.5-6¡ã; PhOCH2, 73, 106-8¡ã; AcNHCH2, 92.5, 108-11¡ã; BzNHCH2 (V), 89.5, 132-4¡ã; 4-AcNHC6H4SO2NHCH2, 80, 152-4¡ã; 2-phenyl-4-quinolyl, 39.5, 165-6¡ã. V was prepared by using 20% excess of II, the others by using 100% excess of II. III and IV were prepared by keeping a mixture of the resp. I and II at room temperature 24 hrs. For the others an approx. 1-2M solution of I in a suitable solvent was left with II 24 hrs.

Lodz Towarz. Nauk., Wydzial III, Acta Chim. published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Product Details of C3H12Cl2N2.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia