Khalaf, Ali Ali published the artcileModern Friedel-Crafts chemistry. VII. Group participation in the rate-determining ionization step during inter- and intramolecular Friedel-Crafts alkylations and the mechanism of formation of 1-methyltetralin during the aluminum chloride-catalyzed reaction of 1-chloro-2-methyl-4-phenylbutane, Recommanded Product: 2-Methyl-4-phenylbutanoic acid, the publication is Revue Roumaine de Chimie (1974), 19(8), 1361-72, database is CAplus.
Aryl group participation in the rate-determining ionization step during intramol. Friedel-Crafts alkylation of benzene with Me2CBrCH2Br and Me2CPhCH2Cl and intramol. alkylation of Ph(CH2)4Cl, Ph(CH2)2CHMeCH2Cl (I), and p-MeC6H4CMe2CH2CH2Cl over AlCl3/MeNO2 was affected by the relative positions of the aryl and halogen groups. The formation of 1-methyltetralin from I, in addition to 1,1-dimethylindene, involved an AlCl3-induced hydride ion abstraction mechanism.
Revue Roumaine de Chimie published new progress about 1949-41-3. 1949-41-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene, name is 2-Methyl-4-phenylbutanoic acid, and the molecular formula is C11H14O2, Recommanded Product: 2-Methyl-4-phenylbutanoic acid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia