Tyrra, Wieland E.’s team published research in Journal of Fluorine Chemistry in 112 | CAS: 1206-46-8

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C65H82N2O18S2, Recommanded Product: Trimethyl(perfluorophenyl)silane.

Tyrra, Wieland E. published the artcileOxidative perfluoroorganylation methods in group 12-16 chemistry The reactions of haloperfluoroorganics and In and InBr, a convenient new route to AgRf (Rf = CF3, C6F5) and reactions of AgRf with group 12-16 elements, Recommanded Product: Trimethyl(perfluorophenyl)silane, the publication is Journal of Fluorine Chemistry (2001), 112(1), 149-152, database is CAplus.

Perfluoroiodo organics RfI [Rf = n-CnF2n+1 (n = 1, 2, 3, 4, 6), i-C3F7, C6F5] and C6F5Br react with elemental In in polyethers or THF to give spectroscopic evidence for compounds InIIRfX (X = I, Br). All isolation attempts led to decomposition into InIII(Rf)2I and InII. In contrast, the reaction of In, 0.5Br2 and C6F5Br in THF selectively and quant. yielded In(C6F5)Br2¡¤2THF which was structurally characterized. The reaction of In(C6F5)Br2¡¤2THF and acetylacetone (Hacac) quant. gave the distorted octahedral mol. In(acac)Br2¡¤2THF. Perfluoroorganosilver(I) compounds Ag(Rf) (Rf = CF3, C6F5) are conveniently and selectively prepared from AgF and Me3SiRf in several nitrile solvents. [PNP][AgI(CF3)2] ([PNP] = bis(triphenylphosphoranyliden)ammonium) is isolated from the reaction mixture after addition of one equivalent of [PNP]Cl. Using excess of [PNP]Cl, [PNP][AgI(CF3)Cl] is formed which was characterized by single crystal structure anal. Besides its properties as a nucleophilic perfluoroorganylating reagent, AgRf exhibits to be an excellent oxidative perfluoroorganylation reagent in reactions with various elements of groups 12-16 to give the corresponding perfluoroorgano element compounds in moderate to excellent yields leaving elemental Ag.

Journal of Fluorine Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C65H82N2O18S2, Recommanded Product: Trimethyl(perfluorophenyl)silane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia