Cheng, Stephen C. published the artcileElectrochemical and IR Spectroelectrochemical Studies of the Electrocatalytic Reduction of Carbon Dioxide by [Ir2(dimen)4]2+ (dimen = 1,8-Diisocyanomenthane), Formula: C17H37NO3, the publication is Inorganic Chemistry (1996), 35(26), 7704-7708, database is CAplus.
The electrocatalytic reactions of carbon dioxide that are catalyzed by [Ir2(dimen)4]2+ (dimen = 1,8-diisocyanomenthane) were studied with cyclic voltammetry and IR spectroelectrochem. The hexafluorophosphate (PF6–) salt and the tetraphenylborate (BPh4–) salt are electrocatalysts for carbon dioxide reduction IR spectroelectrochem. allowed the identification of the carbon dioxide reduction products and provided information about the mechanism(s) of the reduction Bicarbonate and formate were identified as the electrocatalytic carbon dioxide reaction products by comparing the IR bands observed by spectroelectrochem. with authentic samples of tetrabutylammonium formate, tetrabutylammonium oxalate, and tetrabutylammonium bicarbonate. Formate arises from a net two-electron reduction of carbon dioxide that produces free formate and a formate complex of [Ir2(dimen)4]2+. Bicarbonate results from the reaction of hydroxide (produced when residual water is reduced to hydrogen) with carbon dioxide.
Inorganic Chemistry published new progress about 17351-62-1. 17351-62-1 belongs to catalysis-chemistry, auxiliary class Salt,Amine, name is Tetrabutylammonium hydrogencarbonate, and the molecular formula is C17H37NO3, Formula: C17H37NO3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia