Synthesis and properties of porphyrin-functionalized poly(bithiophenes) was written by Schaferling, M.;Bauerle, P.. And the article was included in Synthetic Metals in 1999.Name: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol The following contents are mentioned in the article:
The linkage of a meso-tetraphenylporphyrin (TPP) derivative to an ¦Ø-bromoalkyl substituted bithiophene by ether formation leads to new porphyrin-functionalized bithiophenes. After metalation of the porphyrin moiety the monomers are polymerized by electrooxidation to the corresponding metalloporphyrin-functionalized poly(bithiophenes). Electrochem. and optical characterization of the polymer films reveal the superimposition of the redox and (electro) optical properties of each active unit. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Name: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol).
4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. The atoms and molecules used as ligands are almost always those that are capable of functioning as the electron-pair donor in the electron-pair bond (a coordinate covalent bond) formed with the metal atom. Replacing precious metals with cheaper and more environmentally friendly metals is regarded as a highly desirable goal in the field of catalysis.Name: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI