Glycosyl bis-porphyrin conjugates: Synthesis and potential application in PDT was written by Sol, V.;Chaleix, V.;Champavier, Y.;Granet, R.;Huang, Y.-M.;Krausz, P.. And the article was included in Bioorganic & Medicinal Chemistry in 2006.Electric Literature of C47H36N4O The following contents are mentioned in the article:
Syntheses of new glycosylated neutral and cationic porphyrin dimers linked at the meso-position via a flexible hydrocarbon chain are described. A detailed 1H and 13C NMR study allows their complete structural elucidation. The UV-visible, fluorescence and MALDI mass spectra are also presented. Photocytotoxicities of these compounds against K562 leukemia cell line are compared to those of Photofrin II. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Electric Literature of C47H36N4O).
4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. Ligands are classified based on the number of lone pair electrons available for the central metal atom, size and charge like anionic, cationic, neutral, monodentate, bidentate, polydentate ligands. The ability of ligands to engender a variety of useful properties of organometallic complexes is the major enabling force for the discovery of new catalytic reactions, activation of small molecules, dramatically enhanced reactivity.Electric Literature of C47H36N4O
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI