Godeau, Guilhem published the artcileOne-pot Staudinger Ureation reaction to develop superhydrophobic/oleophobic surfaces with urea linkers, SDS of cas: 30670-30-5, the publication is Materials & Design (2017), 116-122, database is CAplus.
In this work, we report for the first time the use of the one-pot Staudinger ureation to link an azido monomer to a perfluorinated amine by taking advantage of a variation of the Staudinger reaction using CO2 as an electrophile to form an isocyanate in-situ. The formed isocyanate directly reacts with various perfluorinated amines to form the corresponding urea. This chem. pathway is successfully used to prepare new perfluorinated monomers. The monomers were then electrodeposited to form structured surfaces with different wetting properties. Various properties were obtained such as: parahydrophobicity, super hydrophobicity, oleophilicity and strong oleophobicity. This study shows the important influence of the perfluorinated chain on both polymerization and surface properties. This work also illustrates the efficiency of the one-pot Staudinger ureation for new urea monomer elaboration.
Materials & Design published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, SDS of cas: 30670-30-5.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia