Schmieder-van de Vondervoort, Lizette published the artcileLow temperature, high conversion, liquid-phase benzylic oxidation with dioxygen by metal/NHPI-catalyzed Co-oxidation with benzaldehyde, Computed Properties of 457-68-1, the publication is European Journal of Organic Chemistry (2003), 578-586, database is CAplus.
A new liquid-phase catalytic oxidation system for the low temperature, high conversion benzylic mono-oxyfunctionalization of 5H-dibenz[b,f]azepine-5-carboxamide (I) into oxcarbazepine with dioxygen has been developed. The method is based on a co-oxidation of I with benzaldehyde in the presence of a four-component catalyst system consisting of Co(OAc)2, Ni(OAc)2, Cr(NO3)3, and N-hydroxyphthalimide (NHPI). The influence of the catalyst system on the formation and decomposition of the crucial hydroperoxide intermediate has been investigated. Based on these results, the role of each of the components in the catalyst system is discussed. The scope of this method for the oxidation of other substrates has been studied, and the results are compared with those obtained by Co/NHPI catalyzed oxidation of these substrates.
European Journal of Organic Chemistry published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C13H10F2, Computed Properties of 457-68-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia