Block, Eric published the artcileMercury(II) and methylmercury(II) complexes of novel sterically hindered thiolates: carbon-13 and mercury-199 NMR studies and the crystal and molecular structures of [MeHg(SC6H2-2,4,6-Pr-iso3)], [Hg(SC6H4-2-SiMe3)2], [Hg(2-SC5H3N-3-SiMe3)2], and [Hg{(2-SC6H4)2SiMe2}]2, Application of 2,4,6-Triisopropylbenzenethiol, the publication is Inorganic Chemistry (1990), 29(17), 3172-81, database is CAplus.
Several series of complexes of the types [MeHg(SR)] and [Hg(SR)2] were synthesized, where the ligands are members of new classes of sterically hindered thiolates, including (triorganosilyl)methanethiols, 2-(triorganosilyl)benzenethiols, 3-(triorganosilyl)pyridine-2-thiols, and bis(2-mercaptophenyl) derivatives Detailed 1H, 13C, and 199Hg NMR studies revealed several general trends. The 199Hg chem. shifts moved upfield in the order [MeHg(SR)] < [Hg(SCR’R”R”’)2] < [Hg(S-aryl)2] < [Hg(S-pyridyl)2]. For the [MeHg(SR)] series of complexes, 1J(Hg-C) correlates with ¦Ä(13C(methyl)) and with the type of thiolate ligand. Anomalous behavior is observed for oligomeric species. There is only a limited correlation of ¦Ä(199Hg) with steric cone angles for a subset of the complexes. The structures of 4 of these complexes, I–IV, were determined by x-ray crystallog.
Inorganic Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Application of 2,4,6-Triisopropylbenzenethiol.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia