McCann, Malachy published the artcileSynthesis, x-ray crystal structure and catalytic activity of the manganese(II) complex [Mn(bdoa)(H2O)3] (bdoaH2 = Benzene-1,2-dioxyacetic acid), Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Polyhedron (1996), 15(13), 2117-20, database is CAplus.
Benzene-1,2-dioxyacetic acid (bdoaH2) reacts with Mn(CH3CO2)2¡¤4H2O in an EtOH-H2O mixture to give the Mn(II) complex [Mn(bdoa)(H2O)3]. The x-ray crystal structure of the complex shows the metal to be pseudo seven-coordinate. The quadridentate bdoa2- dicarboxylate ligand forms an essentially planar girdle around the metal, being strongly bonded transoid by a carboxylate O atom from each of the two carboxylate moieties (mean Mn-O 2.199 ?) and also weakly chelated by the two internal ether O O atoms (mean Mn-O 2.413 ?). The coordination sphere about the Mn is completed by three H2O mols. (mean Mn-O 2.146 ?) lying in a meridional plane orthogonal to that of the bdoa2- ligand. Magnetic, conductivity and voltammetry data for the complex are given, and its use as a catalyst for the disproportionation of H2O2 is described.
Polyhedron published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia