Englich, Ulrich published the artcileSodium and Potassium Triisopropylbenzenethiolates: Influence on Solid-State Structure by Metal and Donor, Formula: C15H24S, the publication is Inorganic Chemistry (1998), 37(2), 283-293, database is CAplus.
The synthesis and characterization of a family of Na and K thiolates [MSTrip]¡Þ (M = Na, K; HSTrip = 2,4,6-triisopropybenzenethiol, n = 1-¡Þ) is described. [Na(PMDTA)STrip]2, 1 (PMDTA = N,N,N’,N”,N”-pentamethyldiethylenetriamine), [(NaSTrip)2(Na(Et2O)STrip)4]¡¤0.5solvent, 2, [Na(TMEDA)STrip]¡Þ, 3 (TMEDA = N,N,N’,N’-tetramethylethylenediamine), [Na(THF)STrip]n, 4 (n = 6 or ¡Þ), [K(dibenzo-18-crown-6)(THF)STrip]¡¤THF, 5, [(KSTrip)2(K(THF)STrip)2(K(THF)2STrip)2], 6, [K(THF)STrip]¡Þ, 7, [(K(THF)STrip)2(K(TMEDA)STrip)2(KSTrip)2]¡¤THF, 8, and [K(PMDTA)STrip]¡Þ, 9, were synthesized by treatment of HSTrip with NaH or KH along with the addition of various donors. The target mols. were characterized by IR, 1H NMR, and depending on solubility, 13C NMR spectroscopy and m.p. Compounds 1–3 and 5–9 were also characterized by single-crystal x-ray crystallog. Anal. of structural data clearly indicates that the structural chem. of the target mols. can be influenced by donor choice, as exemplified by the large structural diversity observed in the target mols.: the use of a crown ether gave the monomeric species 5, whereas the use of a monodentate donor, such as THF, gave the ladder-type polymer 7 or the discrete hexameric compounds 2 and 6. Addition of the bidentate donor TMEDA to a solution of [NaSTrip]¡Þ gave the 1-dimensional zigzag polymer 3, whereas use of the tridentate donor PMDTA gave the dimer 1. Changing from Na to K and use of the tridentate donor PMDTA yielded the 1-dimensional zigzag polymer 9, while employment of a mixture of mono- and bidentate donors (THF and TMEDA) resulted in the asym. coordinate hexamer 8. Crystal data with Mo K¦Á (¦Ë = 0.710 73 ?) at 150 K are as follows: 1, a 13.2300(1), b 10.6176(1), c 19.6262(3) ?, ¦Â 100.449(1)¡ã, V = 2711.19(5) ?3, Z = 4, monoclinic, space group P21/n, 6309 independent reflections, R1 (all data) = 0.1004; 2, a 14.4178(3), b 17.6498(4), c 26.2052(6) ?, ¦Á 89.847(1), ¦Â 77.475(1), ¦Ã 70.189(1)¡ã, V = 6106.3(2) ?3, Z = 2, triclinic, space group P1, 25,722 independent reflections, R1 (all data) = 0.1311; 3, a 9.2702(1), b 20.1017(2), c 25.9256(4) ?, V = 4831.15(10) ?3, Z = 8, orthorhombic, space group Pbca, 5032 independent reflections, R1 (all data) = 0.1125; 5, a 14.196(3), b 15.429(3), c 22.562(5) ?, ¦Á 101.92(2), ¦Â 97.31(3), ¦Ã 114.19(3)¡ã?, V = 4313(2) ?3, Z = 4, triclinic, space group P1, 6592 (I > 2¦Ò(I)) data, R = 0.074; 6, a 15.071(3), b 25.301(5) ?, c 17.866(4) ?, ¦Â 113.01(3)¡ã, V = 6270(3) ?3, Z = 2, monoclinic, space group P21/n, 2332 (I > 2¦Ò(I)) data, R = 0.103; 7, a 11.9079(2), b 14.7672(2), c 24.0448(1) ?, ¦Â 98.220(1)¡ã, Z = 4, monoclinic, space group P21/c, 9693 independent reflections, R1 (all data) = 0.1324; 8, a 18.324(4), b 14.323(3), c 26.300(5) ?, ¦Â 106.39(3)¡ã, Z = 2, monoclinic, space group P21/c, 4511 (I >3¦Ò(I)) data, R = 0.105; 9, a 10.4903(2), b 20.1551(5), c 26.4295(4) ?, Z = 8, orthorhombic.
Inorganic Chemistry published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Formula: C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia