Ayurini, Meri published the artcilePolymer end group control through a decarboxylative cobalt-mediated radical polymerization: new avenues for synthesizing peptide, protein and nanomaterial conjugates, Quality Control of 71989-31-6, the publication is JACS Au (2022), 2(1), 169-177, database is CAplus and MEDLINE.
Cobalt-mediated radical polymerizations (CMRPs) have been initiated by the radical decarboxylation of tetrachlorophthalimide activated esters. This allows for the controlled radical polymerization of activated monomers across a broad temperature range with a single cobalt species, with incorporation of polymer end groups derived from simple carboxylic acids derivatives and termination with an organozinc reagent. This method has been applied to the synthesis of a polymer/graphene conjugate and a water-soluble protein/polymer conjugate, demonstrating the first examples of CMRP in graphene and protein conjugation.
JACS Au published new progress about 71989-31-6. 71989-31-6 belongs to catalysis-chemistry, auxiliary class Amino acide derivatives,pyrrolidine, name is Fmoc-Pro-OH, and the molecular formula is C20H19NO4, Quality Control of 71989-31-6.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia