Menon, Swetha S. published the artcileCopper- Based Metal-Organic Frameworks as Peroxidase Mimics Leading to Sensitive H2O2 and Glucose Detection, Application of 2,2′-Dithiodibenzoic acid, the publication is ChemistrySelect (2018), 3(28), 8319-8324, database is CAplus.
A copper based metal organic framework (MOF) synthesized under solvo-thermal conditions was found to exhibit intrinsic peroxidase-like activity and was established both spectrophotometrically and electrochem. It was found that the catalytic behavior had been consistent with Michaelis-Menten kinetics with a Km value of 0.08 mM with H2O2, relatively lower than that of Horseradish peroxidase enzyme (HRP) ie; 3.7 mM. The suitability of Cu-MOF for sensing H2O2 was investigated by electrochem. means. In the case of electrochem. studies, the Cu-MOF modified GCE (glassy carbon electrode) showed a very high sensitivity of 263¦ÌA mmol-1 cm-2 with a detection limit up to 35 mM for H2O2. The peroxidase mimics can be combined with the enzymic oxidation of glucose for sensing glucose. The detection of H2O2 and glucose using Cu-MOF was found to be highly selective towards the common interfering species.
ChemistrySelect published new progress about 119-80-2. 119-80-2 belongs to catalysis-chemistry, auxiliary class sulfides,Carboxylic acid,Benzene, name is 2,2′-Dithiodibenzoic acid, and the molecular formula is C14H10O4S2, Application of 2,2′-Dithiodibenzoic acid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia