Maurya, Mannar R. published the artcileAmine-functionalized titanium dioxide supported dioxidomolybdenum(VI) complexes as functional model for phenoxazinone synthase enzyme, HPLC of Formula: 13822-56-5, the publication is Catalysis Today (2022), 274-287, database is CAplus.
Two dioxidomolybdenum(VI) complexes, [MoVIO2{H2dfba(bhz)2}(H2O)] (1) and [MoVIO2{H2dfba(fah)2}(H2O)] (2) of ligands H4dfba(bhz)2 (I) and H4dfba(fah)2 (II) (H2dfba = 3,5-diformyl-4-hydroxybenzoic acid, Hbhz = benzoylhydrazide and Hfah = 2-furanoylhydrazide), resp. and their corresponding heterogenized complexes [MoVIO2{Hdfba(bhz)2}(H2O)]@APTMS-TiO2 (3) and [MoVIO2{Hdfba(fah)2}(H2O)]@APTMS-TiO2 (4) supported on amine-functionalized titanium dioxide (APTMS-TiO2, III) have been isolated and characterized by various spectroscopic techniques (FT-IR, UV-vis, diffusion reflectance, 1H and 13C NMR), elemental anal. (C, H and N), thermal, TEM and powder-XRD studies. Single-crystal x-ray study of [MoVIO2{H2dfba(bhz)2}(EtOH)]¡¤EtOH (1a¡¤EtOH) confirms the octahedral structure. Both homogeneous and heterogeneous complexes have been explored as phenoxazinone synthase mimicking catalysts in the oxidation of 2-aminophenol to 2-aminophenoxazine-3-one in acetonitrile in the presence of aqueous H2O2. The kcat value for the phenoxazinone synthase-like activity was 1.46 x 10-3 and 3.26 x 1 0-3 min-1 for catalysts 1 and 2, resp. Catalysts 1, 2, 3 and 4 also gave 91, 86, 94 and 88% yield of 2-aminophenoxazine-3-one (APX), resp., under the optimized reaction conditions.
Catalysis Today published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, HPLC of Formula: 13822-56-5.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia